Chemical elements
  Titanium
    Isotopes
    Energy
    Preparation
    Physical Properties
    Chemical Properties
      Titanium Trifluoride
      Titanium Tetrafluoride
      Hydrofluotitanic acid
      Potassium Titanifluoride
      Sodium Titanifluoride
      Titanium Dichloride
      Titanium Trichloride
      Titanium Tetrachloride
      Titanic Chloride
      Titanium Oxychlorides
      Hydrochlorotitanic Acid
      Addition Compounds of Titanium Tetrachloride
      Titanium Tribromide Hexahydrate
      Titanium Tetrabromide
      Titanic Bromide
      Hydrobromotitanic Acid
      Titanium Chlorobromides
      Titanium Di-iodide
      Titanium Tri-iodide
      Titanium Tetra-iodide
      Titanic Iodide
      Titanium Monoxide
      
Titanium Sesquioxide
      Titanium Dioxide
      Titanic Oxide
      Titanic Hydroxides
      Metatitanic Acid
      Titanates
      Titanium Monosulphide
      Titanium Sesquisulphide
      Titanium Disulphide
      Titanium Sulphates
      Titanous Sulphate
      Titanium Sesquisulphate
      Complex Sulphates of Tervalent Titanium
      Normal Titanic Sulphate
      Potassium Titanisulphate
      Potassium and Ammonium Titanylsulphates
      Titanous Nitride
      Titanic Nitride
      Titanamide
      Titanium Nitrogen Halides
      Titaninitric Acid
      Titanium Phosphide
      Titaniphosphoric Acid
      Titanium Carbide
      Titanium Cyanonitride
      Titanium Thiocyanates
      Titanium Sesquioxalate
      Titanitartrates and Allied Salts
      Titanium Silicide
      Pertitanates

Complex Sulphates of Tervalent Titanium






The above compound of titanium sesquisulphate and sulphuric acid may be alternatively described as titanosulphuric acid; the alkali salts of this acid will then be complex rather than double salts. By combination with rubidium and ammonium sulphates the following titanosulphates have been obtained by Stahler: 3Ti2(SO4)3.Rb2SO4.24H2O; 3Ti2(SO4)3.(NH4)2SO4.18H2O. In addition to these a sodium salt of the composition Ti2(SO4)3.Na2SO4.5H2O has been obtained in violet crystals by the electrolytic reduction of sodium titanic sulphate solution. It is prepared technically and used as a reducing agent. Perchlorates can be reduced and estimated by its means.

Besides these salts titanium sesquisulphate forms alums, which, like other alums, diminish in solubility with increase in electropositiveness of the alkali metal. The rubidium and caesium salts, Rb2SO4.Ti2(SO4)3.24H2O and Cs2SO4.Ti2(SO4)3.24H2O have been prepared by Piccini.


© Copyright 2008-2012 by atomistry.com