Chemical elements
  Titanium
    Isotopes
    Energy
    Preparation
    Physical Properties
    Chemical Properties
      Titanium Trifluoride
      Titanium Tetrafluoride
      Hydrofluotitanic acid
      Potassium Titanifluoride
      Sodium Titanifluoride
      Titanium Dichloride
      Titanium Trichloride
      Titanium Tetrachloride
      Titanic Chloride
      Titanium Oxychlorides
      Hydrochlorotitanic Acid
      Addition Compounds of Titanium Tetrachloride
      Titanium Tribromide Hexahydrate
      Titanium Tetrabromide
      Titanic Bromide
      Hydrobromotitanic Acid
      Titanium Chlorobromides
      Titanium Di-iodide
      Titanium Tri-iodide
      Titanium Tetra-iodide
      Titanic Iodide
      Titanium Monoxide
      
Titanium Sesquioxide
      Titanium Dioxide
      Titanic Oxide
      Titanic Hydroxides
      Metatitanic Acid
      Titanates
      Titanium Monosulphide
      Titanium Sesquisulphide
      Titanium Disulphide
      Titanium Sulphates
      Titanous Sulphate
      Titanium Sesquisulphate
      Complex Sulphates of Tervalent Titanium
      Normal Titanic Sulphate
      Potassium Titanisulphate
      Potassium and Ammonium Titanylsulphates
      Titanous Nitride
      Titanic Nitride
      Titanamide
      Titanium Nitrogen Halides
      Titaninitric Acid
      Titanium Phosphide
      Titaniphosphoric Acid
      Titanium Carbide
      Titanium Cyanonitride
      Titanium Thiocyanates
      Titanium Sesquioxalate
      Titanitartrates and Allied Salts
      Titanium Silicide
      Pertitanates

Titanium Sesquisulphate, Ti2(SO4)3






According to Glatzel the octahydrate Ti2(SO4)3.8H2O is obtained by dissolving the metal in dilute sulphuric acid, and evaporating the solution. A violet solution, is said to be formed which on being concentrated becomes blue and deposits tufted crystals. According to Stahler and Wirthwein, however, the sesquisulphate is not formed in this way; but when a concentrated solution of the trichloride is repeatedly evaporated at 60° C. with dilute sulphuric acid in a vacuum, a crystalline precipitate of titanium sesquisulphate sulphuric acid is formed, which, after washing with acetic acid and ether, has the composition 3Ti2(SO4)3.H2SO4.25H2O. The same product is obtained as a violet crystalline powder when titanic sulphate dissolved in 50 per cent, sulphuric acid is reduced electrolytically for five or six hours. The anhydrous sesquisulphate, Ti2(SO4)3, is separated as a green, crystalline powder, insoluble in water, alcohol, ether, or concentrated sulphuric acid, by the repeated evaporation of a dilute sulphuric acid solution of titanium sesquisulphate sulphuric acid in absence of air. Titanium sesquisulphate closely resembles the corresponding vanadium sulphate, V2(SO4)3, in properties, and in the compounds it forms with sulphuric acid and other sulphates; it is decomposed by heat into SO2, SO3, and TiO2.


© Copyright 2008-2012 by atomistry.com